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专业科研实验室

名:王自坤  

出生年月:1987.10

学历学位:研究生/博士

称:副教授

行政职务:无

所在系所:东北师范大学化学学院

联系电话  

电子邮件:490331996@qq.com

指导研究生所属学科及导师类别:有机化学/高分子化学、硕士生导师

通讯地址:长春市人民大街5268

研究领域:有机合成及高分子合成


个人简介

    王自坤,副教授,硕士生导师,博士。作为项目负责人或骨干承担或已完成课题十余项。以第一作者或通讯作者身份发表论文16篇。


教育与培训:

    20099月至20146月,中国科学院长春应用化学研究所,硕博连读,博士学位。

    20059月至20097月,河北工业大学 应用化学专业,学士学位;


工作经历:

    20187月至今, 东北师范大学 化学学院,副教授

    20147月至20186月, 中国科学院长春应用化学研究所,助理研究员


代表性科研项目

    (1) 吉林省科技厅,优秀青年人才基金项目,20190103128JH,α-重氮-1,3-二羰基化合物对羧酸的O-H插入反应在高分合成中的应用,2019-12020-127万元,已结题,主持

    (2) 国家自然科学基金委员会,青年项目,21604082,改进型Wolff环缩合在含1,2,3-三氮唑高分子合成中的应用,2017-012019-1220万元,已结题,主持


代表性论文:

    (1) Zikun Wang(#), Zhansong Zhang(#), Wanjun Zhao, Paramasivam Sivaguru, Giuseppe Zanoni, Yingying Wang, Edward A. Anderson, and Xihe Bi*. Synthetic exploration of sulfinyl radicals using sulfinyl sulfones. Nature Commun. 2021, 12, 5244.

    (2) Zikun Wang, Nikolaos V. Tzouras, Steven P. Nolan,* and Xihe Bi*. Silver N-heterocyclic carbenes: emerging powerful catalysts. Trends in Chemistry. 2021, 3, 674-685.

    (3) Xueying Zhang, Zhansong Zhang, Jinna Song,* Zikun Wang*. Reductive radical-initiated 1,2-C migration assisted by azidyl group. Chem. Sci. 2020, 11, 7921-7926.

    (4) Zikun Wang(#), Linxuan Li(#), Xueying Zhang, and Xihe Bi*. Silver-catalyzed unstrained C(CO)-alkyl bond scission via [3+2]/retro-[3+2] cycloaddition of ketones. Sci. Chin. Chem. 2021, 64, 1157-1163.

    (5) Fanhua Yi, Wanjun Zhao, Zikun Wang* and Xihe Bi*. Silver-Mediated [3 + 2] Cycloaddition of Alkynes and N-Isocyanoiminotriphenylphosphorane: Access to Monosubstituted Pyrazoles. Org. Lett. 2019, 21, 3158-3161.

    (6) Yan Wang, Baobiao Dong, Zikun Wang*, Xuefeng Cong and Xihe Bi*. Silver-Catalyzed Reduction of Quinolines in Water. Org. Lett. 2019, 21, 3631-3634.

    (7) Zikun Wang, Xihe Bi,* Peiqiu Liao and Dewen Dong*. Copper-catalyzed Formal O-H Insertion of α-Diazo-1,3-dicarbonyl Compounds to Carboxylic Acids with The Assistance of Isocyanide. Chem. Commun. 2014, 50, 3976-3978.

    (8) Zikun Wang, Xihe Bi,* Peiqiu Liao, Xu Liu and Dewen Dong*. Cu()-Catalyzed Cyclization of α-Diazo-β-oxoamides with Amindes Leading to Pyrrol-3(2H)-ones. Chem. Commun. 2013, 49, 1309-1311.

    (9) Zikun Wang, Xihe Bi,* Peiqiu Liao, Rui Zhang, Yongjiu Liang, and Dewen Dong*. Intramolecular Hydrogen Bonding-Assisted Cyclocondensation of α-Diazoketones with Various Amines: A Strategy for Highly Efficient Wolff 1,2,3-Triazole Sythesis. Chem. Commun. 2012, 48, 7076-7078.

    (10) Binbin Liu, Qingmin Song, Zhaohong Liu* and Zikun Wang*. Silver-catalyzed oxyphosphorylation of unactivated alkynes via hydroazidation. Adv. Synth. Catal. 2021, 363, 3214-3219.

    (11) Zikun Wang, Youhua Tao, Zhen Wang, and Jingling Yan*. Synthesis and Characterization of Poly(N-vinyl-1,2,3-triazole)s Derived from Monomers Obtained by Highly Efficient Wolffs Cyclocondensation. Polym. Chem. 2016, 7, 3172-3178. (IF 5.582, SCI二区;JCR一区)

    (12) Xin Wang, Yuanli Ding, Youhua Tao, Zikun Wang,* Zhen Wang,* Jingling Yan*. Polycondensation of bis(α-diazo-1,3-dicarbonyl)compounds with dicarboxylic acids: an efficient access to functionalized alternating polyesters. Polym. Chem. 2020, 11, 1708-1712. (IF 5.582, SCI二区;JCR一区)

    (13) Zixu Zhang, Zikun Wang*, Hongliang Mu, Xin Wang, Yunhui Li, Jingling Yan, and Zhen Wang. A Novel Approach to 1,2,3-Triazole Grafted Chitosans via Modified Wolffs Cyclocondensation. European Polymer Journal 2018, 98, 492-498. (IF 4.598, SCI二区;JCR一区)

    (14) Minghui Tong, Xinyu Zhang, Yeming Wang,* Zikun Wang*. Advances in reaction of iodonium ylides. Chinese J. Org. Chem. 2021, 41, 126-143. (IF 1.344)

    (15) Lingnan Chen, Shanshan Cao, Jingping Zhang* and Zikun Wang*. Silver-promoted regio- and stereoselective aminocyanation of alkynes for the synthesis of β-aminoacrylonitriles using N-isocyanoiminotriphenylphosphorane. Tetrahedron Lett. 2019, 60, 1678-1681. (IF 2.415)

    (16) Xiaodong Ji, Jingling Yan, Xiuju Liu, Zikun Wang*, and Zhen Wang. Synthesis and Properties of Polyimides Derived from Bis(4-aminophenyl)isohexides. High Performance Polymers 2016, 29, 197-204.

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